Pressure-induced superconducting state of europium metal at low temperatures.

نویسندگان

  • M Debessai
  • T Matsuoka
  • J J Hamlin
  • J S Schilling
  • K Shimizu
چکیده

Divalent Eu (4f;{7}, J=7/2) possesses a strong local magnetic moment which suppresses superconductivity. Under sufficient pressure it is anticipated that Eu will become trivalent (4f;{6}, J=0) and a weak Van Vleck paramagnet, thus opening the door for a possible superconducting state, in analogy with Am metal (5f;{6}, J=0) which superconducts at 0.79 K. We present ac susceptibility and electrical resistivity measurements on Eu metal for temperatures 1.5-297 K to pressures as high as 142 GPa. At approximately 80 GPa Eu becomes superconducting at T_{c} approximately 1.8 K; T_{c} increases linearly with pressure to 2.75 K at 142 GPa. Eu metal thus becomes the 53rd known elemental superconductor in the periodic table.

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عنوان ژورنال:
  • Physical review letters

دوره 102 19  شماره 

صفحات  -

تاریخ انتشار 2009